Publications/Patents

2021
Keneth ES, Kamyshny A, Totaro M, Beccai L, Magdassi S. 3D Printing Materials for Soft Robotics. Advanced Materials [Internet]. 2021;33 (19) :2003387 - 2003387. Publisher's VersionAbstract
Soft robotics is a growing field of research, focusing on constructing motor-less robots from highly compliant materials, some are similar to those found in living organisms. Soft robotics has a high potential for applications in various fields such as soft grippers, actuators, and biomedical devices. 3D printing of soft robotics presents a novel and promising approach to form objects with complex structures, directly from a digital design. Here, recent developments in the field of materials for 3D printing of soft robotics are summarized, including high-performance flexible and stretchable materials, hydrogels, self-healing materials, and shape memory polymers, as well as fabrication of all-printed robots (multi-material printing, embedded electronics, untethered and autonomous robotics). The current challenges in the fabrication of 3D printed soft robotics, including the materials available and printing abilities, are presented and the recent activities addressing these challenges are also surveyed.
Kam D, Braner A, Abouzglo A, Larush L, Chiappone A, Shoseyov O, Magdassi S. 3D Printing of Cellulose Nanocrystal-Loaded Hydrogels through Rapid Fixation by Photopolymerization. Langmuir [Internet]. 2021. Publisher's VersionAbstract
New ink compositions for direct ink writing (DIW) printing of hydrogels, combining superior rheological properties of cellulose nanocrystals (CNCs) and a water-compatible photoinitiator, are presented. Rapid fixation was achieved by photopolymerization induced immediately after the printing of each layer by 365 nm light for 5 s, which overcame the common height limitation in DIW printing of hydrogels, and enabled the fabrication of objects with a high aspect ratio. CNCs imparted a unique rheological behavior, which was expressed by orders of magnitude difference in viscosity between low and high shear rates and in rapid high shear recovery, without compromising ink printability. Compared to the literature, the presented printing compositions enable the use of low photoinitiator concentrations at a very short build time, 6.25 s/mm, and are also curable by 405 nm light, which is favorable for maintaining viability in bioinks.
Xu Q, Ke Y, Feng C, Chen C, Wen Z, Wang H, Sun M, Liu X, Liu H, Magdassi S, et al. Anisotropic localized surface plasmon resonance of vanadium dioxide rods in flexible thermochromic film towards multifunctionality. Solar Energy Materials and Solar Cells [Internet]. 2021;230 :111163 - 111163. Publisher's Version
Ke Y, Zhang B, Wang T, Zhong Y, Vu TD, Wang S, Liu Y, Magdassi S, Ye X, Zhao D, et al. Manipulating atomic defects in plasmonic vanadium dioxide for superior solar and thermal management. Materials Horizons [Internet]. 2021;8 (6) :1700 - 1700. Publisher's VersionAbstract
A pioneering perspective to modify the VO 2 LSPR at an atomic level, resulting in high tunability and great potential in several applications targeting light and thermal management. Vanadium dioxide (VO 2 ) is a unique active plasmonic material due to its intrinsic metal–insulator transition, remaining less explored. Herein, we pioneer a method to tailor the VO 2 surface plasmon by manipulating its atomic defects and establish a universal quantitative understanding based on seven representative defective VO 2 systems. Record high tunability is achieved for the localized surface plasmon resonance (LSPR) energy (0.66–1.16 eV) and transition temperature range (40–100 °C). The Drude model and density functional theory reveal that the charge of cations plays a dominant role in the numbers of valence electrons to determine the free electron concentration. We further demonstrate their superior performances in extensive unconventional plasmonic applications including energy-saving smart windows, wearable camouflage devices, and encryption inks.
Goei R, Ong AJ, Hao TJ, Yi LJ, Kuang LS, Mandler D, Magdassi S, Tok AIY. Novel Nd–Mo co-doped SnO2/α-WO3 electrochromic materials (ECs) for enhanced smart window performance. Ceramics International. 2021;47 (13) :18433 - 18442.Abstract
In an urbanized city, about a third of total electrical consumption is allocated for indoor lighting and air conditioning system in residential and commercial buildings. The majority of the worldwide energy generation comes from burning of non-renewable fossil fuel which is not sustainable in the long run. The use of smart windows technology may catalyze the effort to reduce energy consumption of building and houses. More than 50% of heat entering a building through windows originate from the solar radiation in the near infrared (NIR) region. This candidate smart window material must exhibit dual-band (visible and NIR) modulation that allows selective modulation of NIR heat without affecting visible light transmission. A good electrochromic material in this respect should possess high visible light transmission, high NIR modulation, fast switching between colored and bleached state, and good stability over prolonged usage. In this work, we propose a novel Nd–Mo co-doped SnO2/α-WO3 electrochromic materials (ECs). As compared to the traditional SnO2/α-WO3 ECs, our Nd–Mo co-doped SnO2/α-WO3 ECs exhibits up to 90% visible light transparency (at λ = 600 nm), 62% NIR modulation (at wavelength 1200 nm), high coloration efficiency (~200 cm2 C−1), fast switching time with only 31% electrochromic performance drop (vs 59% of undoped sample) after up to 1000 reversible cyclic test. The enhanced electrochromic performance comes from the presence of Nd–Mo co-dopants that limit the trapping of Li + ion within α-WO3 framework, reduce the extent of crystallization of α-WO3 layer and enhancement of the electronic conductivity by transferring their excess electron to the conduction band of the SnO2. To the best of the authors’ knowledge, the present composition of ECs offers one of the better candidate materials for electrochromic to be used as thermal management layers on smart windows application.
Rosental T, Mizrahi S, Kamyshny A, Magdassi S. Particle-free compositions for printing dense 3D ceramic structures by digital light processing. Virtual and Physical Prototyping [Internet]. 2021 :1 - 12. Publisher's VersionAbstract
UV-curable particle-free ceramic compositions for stereolithography-based 3D printing technologies present a promising alternative to the commonly used particle-based compositions. So far, such compositions were mainly based on solutions of pre-ceramic polymers which limit their applications to silicon-containing materials. However, the application of particle-free inks for the fabrication of other ceramic materials, in particular dense polycrystalline ones, is very little explored. We present a new and general fabrication approach based on all-solution compositions, by combining sol–gel chemistry and photopolymerization, for obtaining dense 3D ceramic structures by DLP printing. The process is demonstrated here for the fabrication of barium titanate (BaTiO3). By using chelating solvent and monomer, a stable UV-curable solution is obtained. An aging period of 8–14 days was crucial for obtaining dense ceramic objects without any secondary phases. The heat treatment was found to affect the microstructure, density and hardness of the resulting ceramics. The presented process enables obtaining objects free of carbon materials, having a density as high as 98% of the theoretical value, and a hardness of 4.3 GPa.
Waiskopf N, Magdassi S, Banin U. Quantum Photoinitiators: Toward Emerging Photocuring Applications. Journal of the American Chemical Society [Internet]. 2021;143 (2) :577 - 587. Publisher's VersionAbstract
Semiconductor nanocrystals are promising photocatalysts for a wide range of applications, ranging from alternative fuel generation to biomedical and environmental applications. This stems from their diverse properties, including flexible spectral tunability, stability, and photocatalytic efficiencies. Their functionality depends on the complex influence of multiple parameters, including their composition, dimensions, architecture, surface coating, and environmental conditions. A particularly promising direction for rapid adoption of these nanoparticles as photocatalysts is their ability to act as photoinitiators (PIs) for radical polymerization. Previous studies served to demonstrate the proof of concept for the use of quantum confined semiconductor nanocrystals as photoinitiators, coining the term Quantum PIs, and provided insights for their photocatalytic mechanism of action. However, these early reports suffered from low efficiencies while requiring purging with inert gases, use of additives, and irradiation by high light intensities with very long excitation durations, which limited their potential for real-life applications. The progress in nanocrystal syntheses and surface engineering has opened the way to the introduction of the next generation of Quantum PIs. Herein, we introduce the research area of nanocrystal photocatalysts, review their studies as Quantum PIs for radical polymerization, from suspension polymerization to novel printing, as well as in a new family of polymerization techniques, of reversible deactivation radical polymerization, and provide a forward-looking view for the challenges and prospects of this field.
Leow SW, Li W, Tan JMR, Venkataraj S, Tunuguntla V, Zhang M, Magdassi S, Wong LH. Solution-Processed Semitransparent CZTS Thin-Film Solar Cells via Cation Substitution and Rapid Thermal Annealing. Solar RRL [Internet]. 2021 :2100131 - 2100131. Publisher's VersionAbstract
Semitransparent solar cells are able to capitalize on land scarcity in urban environments by co-opting windows and glass structures as power generators, thereby expanding the capacity of photovoltaics to meet energy needs. To be successful, devices must be efficient, possess good visual transparency, long-term stability, and low cost. Copper zinc tin sulfide is a promising thin-film material that consists of earth-abundant elements. For optical transparency, the usual molybdenum back contact is replaced with a transparent conducting oxide (TCO). However, due to subsequent high-temperature annealing, the TCO degrades, losing conductivity, or forms a poor interface with CZTS. Lower temperatures mitigate this issue but hinder grain growth in CZTS films. Herein, cadmium substitution and silver and sodium doping are used to aid grain growth and improve film quality at lower annealing temperatures. Thin molybdenum is sputtered on TCO to help improve the interface transition postannealing by conversion to MoS2. Rapid thermal processing is used to minimize high-temperature exposure time to preserve the TCO. With these methods, a semitransparent device with a front illumination efficiency of 2.96% is demonstrated.
Ge Q, Chen Z, Cheng J, Zhang B, Zhang YF, Li H, He X, Yuan C, Liu J, Magdassi S, et al. 3D printing of highly stretchable hydrogel with diverse UV curable polymers. Science Advances [Internet]. 2021;7 (2) :eaba4261 - eaba4261. Publisher's VersionAbstract
Hydrogel-polymer hybrids have been widely used for various applications such as biomedical devices and flexible electronics. However, the current technologies constrain the geometries of hydrogel-polymer hybrid to laminates consisting of hydrogel with silicone rubbers. This greatly limits functionality and performance of hydrogel-polymer–based devices and machines. Here, we report a simple yet versatile multimaterial 3D printing approach to fabricate complex hybrid 3D structures consisting of highly stretchable and high–water content acrylamide-PEGDA (AP) hydrogels covalently bonded with diverse UV curable polymers. The hybrid structures are printed on a self-built DLP-based multimaterial 3D printer. We realize covalent bonding between AP hydrogel and other polymers through incomplete polymerization of AP hydrogel initiated by the water-soluble photoinitiator TPO nanoparticles. We demonstrate a few applications taking advantage of this approach. The proposed approach paves a new way to realize multifunctional soft devices and machines by bonding hydrogel with other polymers in 3D forms.
Caprioli M, Roppolo I, Chiappone A, Larush L, Pirri CF, Magdassi S. 3D-printed self-healing hydrogels via Digital Light Processing. Nature Communications [Internet]. 2021;12 (1) :1 - 9. Publisher's VersionAbstract
Self-healing hydrogels may mimic the behavior of living tissues, which can autonomously repair minor damages, and therefore have a high potential for application in biomedicine. So far, such hydrogels have been processed only via extrusion-based additive manufacturing technology, limited in freedom of design and resolution. Herein, we present 3D-printed hydrogel with self-healing ability, fabricated using only commercially available materials and a commercial Digital Light Processing printer. These hydrogels are based on a semi-interpenetrated polymeric network, enabling self-repair of the printed objects. The autonomous restoration occurs rapidly, at room temperature, and without any external trigger. After rejoining, the samples can withstand deformation and recovered 72% of their initial strength after 12 hours. The proposed approach enables 3D printing of self-healing hydrogels objects with complex architecture, paving the way for future applications in diverse fields, ranging from soft robotics to energy storage.
Gastaldi M, Cardano F, Zanetti M, Viscardi G, Barolo C, Bordiga S, Magdassi S, Fin A, Roppolo I. Functional Dyes in Polymeric 3D Printing: Applications and Perspectives. ACS Materials Letters [Internet]. 2021;3 (1) :1 - 17. Publisher's VersionAbstract
Three-dimensional printing (3DP) is considered among the key-technologies for the next industrial revolution, with considerable effects on production processes, economy, and society. In this context, the most relevant part of the market consists of polymeric 3D printing. The 3D printable liquids are composed of various components, among them dyes are usually underrated because they are introduced merely for aesthetical reasons or to enhance the objects' resolution. In recent years, the capability of specific dyes to go beyond conventional use and to confer functional properties to 3D printed objects has become an emerging research area. Modifying elastic moduli upon light irradiation, inducing optical and emitting properties in the matrices or conferring temperature responsivity are just few examples of innovative stimuli-responsive materials that can be produced by combining well-designed dyes with the appropriate 3DP printed matrices. In this Review, we discuss and critically analyze the most relevant recent results achieved in the use of smart dyes in the synthesis of stimuli responsive 3D printed polymers.
2020
Dong Y, Wang S, Ke Y, Ding L, Zeng X, Magdassi S, Long Y. 4D Printed Hydrogels: 4D Printed Hydrogels: Fabrication, Materials, and Applications (Adv. Mater. Technol. 6/2020). Advanced Materials Technologies [Internet]. 2020;5 (6) :2070037 - 2070037. Publisher's Version
Vinetsky Y, Jambu J, Mandler D, Magdassi S. Cnt-based solar thermal coatings: Absorptance vs. emittance. Coatings [Internet]. 2020;10 (11) :1 - 12. Publisher's VersionAbstract
A novel approach for fabricating selective absorbing coatings based on carbon nanotubes (CNTs) for mid-temperature solar–thermal application is presented. The developed formulations are dispersions of CNTs in water or solvents. Being coated on stainless steel (SS) by spraying, these formulations provide good characteristics of solar absorptance. The effect of CNT concentration and the type of the binder and its ratios to the CNT were investigated. Coatings based on water dispersions give higher adsorption, but solvent-based coatings enable achieving lower emittance. Interestingly, the binder was found to be responsible for the high emittance, yet, it is essential for obtaining good adhesion to the SS substrate. The best performance of the coatings requires adjusting the concentration of the CNTs and their ratio to the binder to obtain the highest absorptance with excellent adhesion; high absorptance is obtained at high CNT concentration, while good adhesion requires a minimum ratio between the binder/CNT; however, increasing the binder concentration increases the emissivity. The best coatings have an absorptance of ca. 90% with an emittance of ca. 0.3 and excellent adhesion to stainless steel.
Chew KH, Farraj Y, Magdassi S. Electroless Plating with Copper Complex Ink as a Seed, in 2020 IEEE 22nd Electronics Packaging Technology Conference, EPTC 2020. Institute of Electrical and Electronics Engineers Inc. ; 2020 :36 - 40.Abstract
Electroless or electrolytic deposition processes require the use of a very costly catalyst, usually palladium, as a seed material. Here we present the use of a copper complex as a very efficient replacement for the conventional catalysts, which can be directly printed by various technologies such as screen, gravure, and inkjet, on both 2D and 3D substrates. The copper complex can be reduced to pure copper upon short exposure to low-temperature plasma, by heating under inert atmosphere or via photonic sintering. By combining the complex with electroless plating (EP), a resistivity as low as 2.38.cm which corresponds to 72% conductivity of bulk copper can be achieved
Nowogrodski C, Simon I, Magdassi S, Shoseyov O. Fabrication of second skin from keratin and melanin. Polymers [Internet]. 2020;12 (11) :1 - 13. Publisher's VersionAbstract
Second skin is a topically applied, skin-conforming material that mimics human skin properties and bears potential cosmetic and e-skin applications. To successfully integrate with natural skin, characteristics such as color and skin features must be matched. In this work, we prepared bio-based skin-like films from cross-linked keratin/melanin films (KMFs), using a simple fabrication method and non-toxic materials. The films retained their stability in aqueous solutions, showed skin-like mechanical properties, and were homogenous and handleable, with non-granular surfaces and a notable cross-linked structure as determined by attenuated total reflection (ATR). In addition, the combination of keratin and melanin allowed for adjustable tones similar to those of natural human skin. Furthermore, KMFs showed light transmittance and UV-blocking (up to 99%) as a function of melanin content. Finally, keratin/melanin ink (KMI) was used to inkjet-print high-resolution images with natural skin pigmented features. The KMFs and KMI may offer advanced solutions as e-skin or cosmetics platforms.
Bera RK, Binyamin Y, Frantz C, Uhlig R, Magdassi S, Mandler D. Fabrication of Self-Cleaning CNT-Based Near-Perfect Solar Absorber Coating for Non-Evacuated Concentrated Solar Power Applications. Energy Technology [Internet]. 2020;8 (12) :2000699 - 2000699. Publisher's VersionAbstract
A near-perfect black solar absorber made of carbon nanotubes (CNTs) prepared by a low-cost wet-deposition method on a reflective metal surface for mid-temperature non-evacuated concentrated solar power (CSP) applications is demonstrated. The dispersed CNTs in an alumina–silica matrix exhibit an absorptance of 0.985 in the entire solar spectrum and emittance of 0.90 in the infrared (IR) region. The coating shows high durability and is super-hydrophilic (0° contact angle) after plasma treatment, without affecting the solar absorptance and excellent coating adhesion. The efficiency of the coating is evaluated by analytical models, which implies that it has higher efficiency at low temperature and at a high solar concentration ratio than that of previously reported selective coatings.
Kaur G, Marmur A, Magdassi S. Fabrication of superhydrophobic 3D objects by Digital Light Processing. Additive Manufacturing. 2020;36 :101669 - 101669.Abstract
The 3D printing process enables to print objects having various functionalities at pre-designed locations in the object. Hereby, we report on the printing of superhydrophobic objects composed of patterns of micropillars. Superhydrophobicity is an important property of surfaces that has applications in various fields such as self-cleaning, drag reduction, increased buoyancy, and air conditioning. Most existing methods for the fabrication of superhydrophobic surfaces are complicated and time-consuming. Here, we performed a simple and cost-effective process for the fabrication of superhydrophobic (SH) objects by Digital Light Processing (DLP) 3D printing. To the best of our knowledge, this is the first study that has used DLP 3D printing to fabricate SH 3D objects without further coating process. We designed a novel ink, which contained non-fluorinated acrylates and Hydrophobic Fumed Silica (HFS). We studied the effects of HFS concentration and pillar-array design for imparting the SH property, which was measured in terms of the contact and rolling angle of water droplets on the surface. As proof of the concept of increased buoyancy by superhydrophobicity, we demonstrated the floatation of the printed SH objects in comparison to their non-SH counterparts even after forcefully submerging them into water.
SHLOMO MAGDASSI, LIRAZ LARUSH, RAFAEL EZRA. Formulated Cannabis Oil Powder By Nanoemulsifycation, Methods Of Producing And Uses Thereof.; 2020. Publisher's VersionAbstract
The invention discloses particular water-dispersible solid formulation of a cannabinoid or a cannabis extract , wherein they are present in the form of a nanoemulsion , and upon dispersion in water said formulation produces nanoparticles (droplets of a submicron size) with an average size of up to about 500 nm. The present disclosure further relates to methods of making thereof , as well as therapeutic applica tions in humans for treating disorders and broader applica tion for a range of medical conditions .
Garcia-Bilbao A, Gómez-Fernández P, Larush L, Soroka Y, Suarez-Merino B, Frušić-Zlotkin M, Magdassi S, Goñi-de-Cerio F. Preparation, characterization, and biological evaluation of retinyl palmitate and Dead Sea water loaded nanoemulsions toward topical treatment of skin diseases. Journal of Bioactive and Compatible Polymers [Internet]. 2020;35 (1) :24 - 38. Publisher's VersionAbstract
Millions of people suffer from different types of skin diseases worldwide. In the last decade, the development of nanocarriers has been the focus of the pharmaceutical and cosmetic industries to enhance the performance of their products, and to meet consumers’ demands. Several delivery systems have been developed to improve the efficiency and minimize possible side effects. In this study, retinyl palmitate and Dead Sea water loaded nanoemulsions were developed as carriers to treat skin conditions such as photoaging, psoriasis, or atopic dermatitis. Toxicity profiles were carried out by means of viability, cell membrane asymmetry study, evaluation of oxidative stress induction (reactive oxygen species), and inflammation via cytokines production with a human keratinocyte cell line (HaCaT) and a mouse embryo fibroblasts cell line (BALB/3T3). Results showed that loaded nanoemulsions were found to be non-cytotoxic under the conditions of the study. Furthermore, no oxidative stress induction was observed. Likewise, an efficacy test of these loaded nanoemulsions was also tested on human skin organ cultures, before and after ultraviolet B light treatment. Viability and caspase-3 production assessment, in response to the exposure of skin explants to the loaded nanoemulsions, indicated non-toxic effects on human skin in culture, both with and without ultraviolet B irradiation. Further the ability of loaded nanoemulsions to protect the skin against ultraviolet B damage was assessed on skin explants reducing significantly the apoptotic activation after ultraviolet B irradiation. Our promising results indicate that the developed loaded nanoemulsions may represent a topical drug delivery system to be used as an alternative treatment for recurrent skin diseases.
Zhou C, Li D, Tan Y, Ke Y, Wang S, Zhou Y, Liu G, Wu S, Peng J, Li A, et al. 3D Printed Smart Windows for Adaptive Solar Modulations. Advanced Optical Materials [Internet]. 2020;8 (11) :2000013 - 2000013. Publisher's VersionAbstract
Vanadium dioxide (VO2) based thermochromic smart window is considered as the most promising approach for economizing building energy consumption. However, the high phase transition temperature (τc), low luminous transmission (Tlum), and solar modulation (ΔTsol) impose an invertible challenge for commercialization. Currently, smart window research surprisingly assumes that the sunlight radiates in one direction which is obviously not valid as most regions receive solar radiation at various angles in different seasons. For the first time, solar elevation angle is considered and 3D printing technology is employed to fabricate tilted microstructures for modulating solar transmission dynamically. To maximize energy-saving performance, the architecture of the structures (tilt, thickness, spacing, and width) and tungsten (W) doped VO2 can be custom-designed according to the solar elevation angle variation at the midday between seasons and tackle the issue of compromised Tlum and ΔTsol with W-doping. The energy consumption simulations in different cities prove the efficiency of such dynamic modulation. This first attempt to adaptively regulate the solar modulation by considering the solar elevation angle together with one of the best reported thermochromic properties (τc = 40 °C, Tlum(average) = 40.8%, ΔTsol = 23.3%) may open a new era of real-world-scenario smart window research.

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