@article { ISI:000265383200115,
	title = {The Elimination of Redundant Constraints in Surprisal Analysis of Unimolecular Dissociation and Other Endothermic Processes},
	journal = {JOURNAL OF PHYSICAL CHEMISTRY A},
	volume = {113},
	year = {2009},
	month = {APR 23},
	pages = {4658-4664},
	abstract = {It is well understood that energy rich polyatomic molecules do not dissociate promptly because the number, P, of their energy states far exceeds the number, N, of the decay channels. In the simplest RRK theory, the fraction N/P is the probability of dissociation. We discuss the distribution of the decay rates of maximal entropy and conclude that it is governed by at most N linearly independent constraints, N < P, or, more typically, N ,
	issn = {1089-5639},
	doi = {10.1021/jp811463h},
	author = {Remacle, F. and LEVINE, RD}
}
