Citation:
Shenhar, R. ; Jeoung, E. ; Srivastava, S. ; Norsten, T. B. ; Rotello, V. M. Crosslinked nanoparticle stripes and hexagonal networks obtained via selective patterning of block copolymer thin films. Advanced Materials 2005, 17, 2206-2210.
Date Published:
SEP 16Abstract:
Robust arrays of ordered nanoparticles (see Figure and cover) have been created by combining two self‐assembly strategies: microphase separation of block copolymers and coordination chemistry. Thin films of a microphase‐separated block copolymer serve as templates for patterning of terpyridine‐functionalized gold nanoparticles. Subsequent treatment with iron salts crosslinks the patterned nanoparticles via the formation of iron–terpyridine complexes.
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