Polyethylene glycols

Polyethylene glycols

PEG300

polyethylene glycol MW 300

wt%     	log P (dynes/cm^2)

2.6		6.36
5.0		6.73
10.0		7.00
15.0		7.23
20.0		7.41
25.0		7.57
30.0		7.71

An equation that fits this data is the following.

log P = a + b * (wt%) ^ c

where a = 4.79, b = 1.28 and c = 0.24

Note that it should be applied only over the range of pressures measured.

PEG400

PEG400 osmotic pressure and its temperature dependance

1) PEG400 osmotic pressure vs. molality at different temperatures

Please use the following reference when using this data. 

Reference - https://doi.org/10.1002/pro.4573. Osmotic pressure was calculated from the water activity data in table S4. 

Wt%15 degrees C20 degrees C25 degrees C35 degrees C45 degrees C
53.693.743.653.703.71
108.558.528.178.248.23
1514.914.713.813.913.8
2023.222.621.021.021.0
2534.032.830.230.030.0
3048.145.942.041.541.2
3566.763.157.356.455.6
4091.986.377.776.274.8
4512511710410299.6
50172159141137133

 

2) PEG400 Osmotic pressure data (atm)

Reference - see Peter Rand.

PEG400 Osmotic pressure data (dyn/cm^2)

wt%     log P (dynes/cm^2)

2.5      6.3
5         6.55
10       6.93
15       7.14
20       7.33
25       7.5
30       7.65

An equation that fits this data is the following.

log P = a + b * (wt%) ^ c where a = 5.29, b = 0.73 and c = 0.34

Note that it should be applied only over the range of pressures measured.

 

PEG600

polyethylene glycol MW 600

wt%		log P (dynes/cm^2)

2.5		6.22
5.0		6.43
10.0		6.80
15.0		7.01
20.0		7.20
25.0		7.38
30.0		7.53
35.0		7.68	
5.0		6.15
10.0		6.72
15.0		6.96
20.0		7.13
25.0		7.30
30.4		7.42
35.2		7.57
40.5		7.64
45.0		7.92
61.5		8.35
67.5		8.49
45.0		7.92
40.0		7.80
5.0		6.34

An equation that fits this data is the following.

log P = a + b * (wt%) ^ c

where a = 5.63, b = 0.33 and c = 0.51

Note that it should be applied only over the range of pressures measured.

	

PEG1000

polyethylene glycol MW 1000

wt%		log P (dynes/cm^2)

5.0		6.07
10.0		6.61
15.0		6.82
20.0		7.08
25.0		7.34
30.0		7.46
35.0		7.55
40.0		7.65
45.0		7.79
50.0		7.89
55.0		7.93
60.0		7.95	
2.5		6.11
5.0		6.27
10.0		6.54
15.0		6.86
20.0		7.05
25.0		7.26
30.0		7.43
35.0		7.58

An equation that fits this data is the following.

log P = a + b * (wt%) ^ c

where a = 4.87, b = 0.80 and c = 0.34

Note that it should be applied only over the range of pressures measured.

	

PEG1500

polyethylene glycol MW 1500

wt%		log P (dynes/cm^2)

5.0		5.92
10.0		6.49
15.0		6.78
20.0		6.89
25.0		7.27
30.0		7.41
35.0		7.38
40.0		7.60
45.0		7.63
50.0		7.83
60.0		8.03
5.0		6.18
10.0		6.52
15.0		6.76
20.0		6.97
25.0		7.18
30.0		7.36
35.0		7.53

An equation that fits this data is the following.

log P = a + b * (wt%) ^ c

where a = 3.72, b = 1.57 and c = 0.24

Note that it should be applied only over the range of pressures measured.

PEG2000

polyethylene glycol MW 2000

wt%		log P (dynes/cm^2)

5.0		6.20
10.0		6.39
15.0		6.70
20.0		6.91
25.0		7.13
30.0		7.32
35.0		7.49
40.0		7.66	
9.9		6.32
15.0		6.60
20.0		6.95
25.0		7.09
30.0		7.28
34.7		7.40	
5.0		6.04
10.0		6.37
15.0		6.79
20.0		6.94	
10.0		6.38
20.0		6.90
30.0		7.32
40.0		7.66
5.0		6.15
5.0		6.14
15.0		6.66
15.0		6.65
15.0		6.63
15.0		6.68
25.0		7.1
25.0		7.11	
35.0		7.50	
35.0		7.51

An equation that fits this data is the following.

log P = a + b * (wt%) ^ c

where a = 5.60, b = 0.18 and c = 0.67

Note that it should be applied only over the range of pressures measured.

PEG3000

polyethylene glycol MW 3000

wt%		log P (dynes/cm^2)

10.0		6.26
15.0		6.61
20.0		6.84
25.0		7.07
30.0		7.28
35.0		7.46

An equation that fits this data is the following.

log P = a + b * (wt%) ^ c

where a = 4.42, b = 0.74 and c = 0.40

Note that it should be applied only over the range of pressures measured.

PEG4000

polyethylene glycol MW 4000

wt%		log P (dynes/cm^2)

5.0		5.98
10.0		6.29
15.0		6.64
20.0		6.86
25.0		7.11
30.0		7.23
35.0		7.40

An equation that fits this data is the following.

log P = a + b * (wt%) ^ c

where a = 4.93, b = 0.50 and c = 0.45

Note that it should be applied only over the range of pressures measured.

PEG6000

polyethylene glycol MW 6000

wt%		log P (dynes/cm^2)

10.0		6.23
15.0		6.51
20.0		6.79
25.0		7.02
30.0		7.23
35.0		7.43

An equation that fits this data is the following.

log P = a + b * (wt%) ^ c

where a = 5.12, b = 0.28 and c = 0.59

Note that it should be applied only over the range of pressures measured.

	

PEG8000 vs T

PEG 8000 Osmotic Pressure Data at various temperatures

PEG8000 Osmotic pressure data, (atm)

Wt%10 degrees C20 degrees C30 degrees C35 degrees C40 degrees C
5.445.407.385.373.367
101.631.441.311.251.19
153.953.433.082.892.74
207.916.786.045.665.33
2514.112.010.710.09.43
3023.319.917.616.615.6
3536.731.327.826.124.7
4056.748.242.940.438.3
4585.872.564.560.857.8
5012610694.389.284.8
54173144127121115
peg8000.pdf28 KB

PEG 10k

polyethylene glycol MW 10,000

wt%		log P (dynes/cm^2)

10.0		6.16
15.0		6.45
20.0		6.75
25.0		7.00
30.0		7.24
35.0		7.43

An equation that fits this data is the following.

log P = a + b * (wt%) ^ c

where a = 4.99, b = 0.29 and c = 0.60

Note that it should be applied only over the range of pressures measured.

PEG 20K

polyethylene glycol MW 20,000

wt%		log P (dynes/cm^2)

1.5		4.59
2.9		4.98
3.6		5.15
4.7		5.34
5.8		5.55
6.3		5.63
7.1		5.76
9.0		5.89
12.1		6.08
13.1		6.18
14.2		6.29
16.0		6.47
18.3		6.70
18.8		6.68
20.8		6.77
21.6		6.83
22.2		6.83
22.8		6.94
19.0		6.68
22.1		6.83
23.7		6.93
25.0		6.94
26.2		7.03
28.8		7.11
32.7		7.26
34.8		7.34
35.6		7.32
38.0		7.45
39.5		7.48
41.7		7.54
43.2		7.59
45.5		7.67
47.5		7.73

An equation that fits this data is the following.

log P = a + b * (wt%) ^ c

where a = 1.57, b = 2.75 and c = 0.21

Note that it should be applied only over the range of pressures measured.


polyethylene glycol MW 20,000
	At a Temperature of 7-8 degrees C

wt%		log P (dynes/cm^2)

15.3		6.56
17.8		6.75
18.3		6.79
19.5		6.82
20.8		6.91
21.3		6.92
22.9		6.99
23.2		7.00
24.3		7.04

Me-PEG2000

METHYLATED polyethylene glycol MW 2000

wt%		log P (dynes/cm^2)

10.3		6.48
15.1		6.72
24.8		7.20
35.5		7.45

An equation that fits this data is the following.

log P = a + b * (wt%) ^ c

where a = 1.34, b = 3.66 and c = 0.14

Note that it should be applied only over the range of pressures measured.