polyethylene glycol MW 300 wt% log P (dynes/cm^2) 2.6 6.36 5.0 6.73 10.0 7.00 15.0 7.23 20.0 7.41 25.0 7.57 30.0 7.71 An equation that fits this data is the following. log P = a + b * (wt%) ^ c where a = 4.79, b = 1.28 and c = 0.24 Note that it should be applied only over the range of pressures measured.
1) PEG400 osmotic pressure vs. molality at different temperatures
Please use the following reference when using this data.
Reference - https://doi.org/10.1002/pro.4573. Osmotic pressure was calculated from the water activity data in table S4.
Wt% | 15 degrees C | 20 degrees C | 25 degrees C | 35 degrees C | 45 degrees C |
5 | 3.69 | 3.74 | 3.65 | 3.70 | 3.71 |
10 | 8.55 | 8.52 | 8.17 | 8.24 | 8.23 |
15 | 14.9 | 14.7 | 13.8 | 13.9 | 13.8 |
20 | 23.2 | 22.6 | 21.0 | 21.0 | 21.0 |
25 | 34.0 | 32.8 | 30.2 | 30.0 | 30.0 |
30 | 48.1 | 45.9 | 42.0 | 41.5 | 41.2 |
35 | 66.7 | 63.1 | 57.3 | 56.4 | 55.6 |
40 | 91.9 | 86.3 | 77.7 | 76.2 | 74.8 |
45 | 125 | 117 | 104 | 102 | 99.6 |
50 | 172 | 159 | 141 | 137 | 133 |
2) PEG400 Osmotic pressure data (atm)
Reference - see Peter Rand.
wt% log P (dynes/cm^2)
2.5 6.3
5 6.55
10 6.93
15 7.14
20 7.33
25 7.5
30 7.65
An equation that fits this data is the following.
log P = a + b * (wt%) ^ c where a = 5.29, b = 0.73 and c = 0.34
Note that it should be applied only over the range of pressures measured.
polyethylene glycol MW 600 wt% log P (dynes/cm^2) 2.5 6.22 5.0 6.43 10.0 6.80 15.0 7.01 20.0 7.20 25.0 7.38 30.0 7.53 35.0 7.68 5.0 6.15 10.0 6.72 15.0 6.96 20.0 7.13 25.0 7.30 30.4 7.42 35.2 7.57 40.5 7.64 45.0 7.92 61.5 8.35 67.5 8.49 45.0 7.92 40.0 7.80 5.0 6.34 An equation that fits this data is the following. log P = a + b * (wt%) ^ c where a = 5.63, b = 0.33 and c = 0.51 Note that it should be applied only over the range of pressures measured.
polyethylene glycol MW 1000 wt% log P (dynes/cm^2) 5.0 6.07 10.0 6.61 15.0 6.82 20.0 7.08 25.0 7.34 30.0 7.46 35.0 7.55 40.0 7.65 45.0 7.79 50.0 7.89 55.0 7.93 60.0 7.95 2.5 6.11 5.0 6.27 10.0 6.54 15.0 6.86 20.0 7.05 25.0 7.26 30.0 7.43 35.0 7.58 An equation that fits this data is the following. log P = a + b * (wt%) ^ c where a = 4.87, b = 0.80 and c = 0.34 Note that it should be applied only over the range of pressures measured.
polyethylene glycol MW 1500 wt% log P (dynes/cm^2) 5.0 5.92 10.0 6.49 15.0 6.78 20.0 6.89 25.0 7.27 30.0 7.41 35.0 7.38 40.0 7.60 45.0 7.63 50.0 7.83 60.0 8.03 5.0 6.18 10.0 6.52 15.0 6.76 20.0 6.97 25.0 7.18 30.0 7.36 35.0 7.53 An equation that fits this data is the following. log P = a + b * (wt%) ^ c where a = 3.72, b = 1.57 and c = 0.24 Note that it should be applied only over the range of pressures measured.
polyethylene glycol MW 2000 wt% log P (dynes/cm^2) 5.0 6.20 10.0 6.39 15.0 6.70 20.0 6.91 25.0 7.13 30.0 7.32 35.0 7.49 40.0 7.66 9.9 6.32 15.0 6.60 20.0 6.95 25.0 7.09 30.0 7.28 34.7 7.40 5.0 6.04 10.0 6.37 15.0 6.79 20.0 6.94 10.0 6.38 20.0 6.90 30.0 7.32 40.0 7.66 5.0 6.15 5.0 6.14 15.0 6.66 15.0 6.65 15.0 6.63 15.0 6.68 25.0 7.1 25.0 7.11 35.0 7.50 35.0 7.51 An equation that fits this data is the following. log P = a + b * (wt%) ^ c where a = 5.60, b = 0.18 and c = 0.67 Note that it should be applied only over the range of pressures measured.
polyethylene glycol MW 3000 wt% log P (dynes/cm^2) 10.0 6.26 15.0 6.61 20.0 6.84 25.0 7.07 30.0 7.28 35.0 7.46 An equation that fits this data is the following. log P = a + b * (wt%) ^ c where a = 4.42, b = 0.74 and c = 0.40 Note that it should be applied only over the range of pressures measured.
polyethylene glycol MW 4000 wt% log P (dynes/cm^2) 5.0 5.98 10.0 6.29 15.0 6.64 20.0 6.86 25.0 7.11 30.0 7.23 35.0 7.40 An equation that fits this data is the following. log P = a + b * (wt%) ^ c where a = 4.93, b = 0.50 and c = 0.45 Note that it should be applied only over the range of pressures measured.
polyethylene glycol MW 6000 wt% log P (dynes/cm^2) 10.0 6.23 15.0 6.51 20.0 6.79 25.0 7.02 30.0 7.23 35.0 7.43 An equation that fits this data is the following. log P = a + b * (wt%) ^ c where a = 5.12, b = 0.28 and c = 0.59 Note that it should be applied only over the range of pressures measured.
PEG 8000 Osmotic Pressure Data at various temperatures
Wt% | 10 degrees C | 20 degrees C | 30 degrees C | 35 degrees C | 40 degrees C |
5 | .445 | .407 | .385 | .373 | .367 |
10 | 1.63 | 1.44 | 1.31 | 1.25 | 1.19 |
15 | 3.95 | 3.43 | 3.08 | 2.89 | 2.74 |
20 | 7.91 | 6.78 | 6.04 | 5.66 | 5.33 |
25 | 14.1 | 12.0 | 10.7 | 10.0 | 9.43 |
30 | 23.3 | 19.9 | 17.6 | 16.6 | 15.6 |
35 | 36.7 | 31.3 | 27.8 | 26.1 | 24.7 |
40 | 56.7 | 48.2 | 42.9 | 40.4 | 38.3 |
45 | 85.8 | 72.5 | 64.5 | 60.8 | 57.8 |
50 | 126 | 106 | 94.3 | 89.2 | 84.8 |
54 | 173 | 144 | 127 | 121 | 115 |
peg8000.pdf | 28 KB |
polyethylene glycol MW 10,000 wt% log P (dynes/cm^2) 10.0 6.16 15.0 6.45 20.0 6.75 25.0 7.00 30.0 7.24 35.0 7.43 An equation that fits this data is the following. log P = a + b * (wt%) ^ c where a = 4.99, b = 0.29 and c = 0.60 Note that it should be applied only over the range of pressures measured.
polyethylene glycol MW 20,000 wt% log P (dynes/cm^2) 1.5 4.59 2.9 4.98 3.6 5.15 4.7 5.34 5.8 5.55 6.3 5.63 7.1 5.76 9.0 5.89 12.1 6.08 13.1 6.18 14.2 6.29 16.0 6.47 18.3 6.70 18.8 6.68 20.8 6.77 21.6 6.83 22.2 6.83 22.8 6.94 19.0 6.68 22.1 6.83 23.7 6.93 25.0 6.94 26.2 7.03 28.8 7.11 32.7 7.26 34.8 7.34 35.6 7.32 38.0 7.45 39.5 7.48 41.7 7.54 43.2 7.59 45.5 7.67 47.5 7.73 An equation that fits this data is the following. log P = a + b * (wt%) ^ c where a = 1.57, b = 2.75 and c = 0.21 Note that it should be applied only over the range of pressures measured.
polyethylene glycol MW 20,000 At a Temperature of 7-8 degrees C wt% log P (dynes/cm^2) 15.3 6.56 17.8 6.75 18.3 6.79 19.5 6.82 20.8 6.91 21.3 6.92 22.9 6.99 23.2 7.00 24.3 7.04
METHYLATED polyethylene glycol MW 2000 wt% log P (dynes/cm^2) 10.3 6.48 15.1 6.72 24.8 7.20 35.5 7.45 An equation that fits this data is the following. log P = a + b * (wt%) ^ c where a = 1.34, b = 3.66 and c = 0.14 Note that it should be applied only over the range of pressures measured.