Citation:
Babu, K. N. ; Massarwe, F. ; Reddy, R. R. ; Eghbarieh, N. ; Jakob, M. ; Masarwa*, A. Unsymmetrical 1,1-Bisboryl Species: Valuable Building Blocks in Synthesis. Molecules 2020, 25, 959.
Abstract:
Unsymmetrical 1,1-bis(boryl)alkanes and alkenes are organo-bismetallic equivalents, which are synthetically important because they allow for sequential selective transformations of C–B bonds. We reviewed the synthesis and chemical reactivity of 1,1-bis(boryl)alkanes and alkenes to provide information for the synthetic community. In the first part of this review, we disclose the synthesis and chemical reactivity of unsymmetrical 1,1-bisborylalkanes. In the second part, we describe the synthesis and chemical reactivity of unsymmetrical 1,1-bis(boryl)alkenes.
Notes:
Invited Review This article belongs to the Special Issue New Insights in Diversity Oriented Synthesis