Stochastically Bundled Dissipators for the Quantum Master Equation

Citation:

Adhikari, S. ; Baer, R. Stochastically Bundled Dissipators for the Quantum Master Equation. J. Chem. Theory Comput. 2025, 21, 4142–4150.
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Stochastically Bundled Dissipators for the Quantum Master Equation

Abstract:

The Lindblad master equation is a fundamental tool for describing the evolution of open quantum systems, but its computational complexity poses a significant challenge, especially for large systems. This article introduces a stochastic representation of the Lindblad dissipator that addresses this challenge by bundling the Lindblad operators. The stochastic dissipator maintains the Lindblad form, ensuring completely positive and trace-preserving dynamics. We demonstrate the effectiveness of this method by considering a Morse oscillator coupled to a spin bath. Our numerical experiments show that a small number of stochastically bundled operators can accurately capture the system’s dynamics, even when the Hilbert space dimension is large. This method offers a new perspective on open quantum systems and provides a computationally efficient way to simulate their dynamics.

Notes:

Publisher: American Chemical Society

Publisher's Version

Last updated on 10/31/2025