Light - Matter Interactions

2012
Jain, P. K. ; Ghosh, D. ; Baer, R. ; Rabani, E. ; Alivisatos, A. P. Near-field manipulation of spectroscopic selection rules on the nanoscale. Proc. Natl. Acad. Sci. U.S.A. 2012, 109, 8016–8019.Abstract

In conventional spectroscopy, transitions between electronic levels are governed by the electric dipole selection rule because electric quadrupole, magnetic dipole, and coupled electric dipole-magnetic dipole transitions are forbidden in a far field. We demonstrated that by using nanostructured electromagnetic fields, the selection rules of absorption spectroscopy could be fundamentally manipulated. We also show that forbidden transitions between discrete quantum levels in a semiconductor nanorod structure are allowed within the near-field of a noble metal nanoparticle. Atomistic simulations analyzed by an effective mass model reveal the breakdown of the dipolar selection rules where quadrupole and octupole transitions are allowed. Our demonstration could be generalized to the use of nanostructured near-fields for enhancing light-matter interactions that are typically weak or forbidden.

jain2012.pdf
2011
Karolewski, A. ; Stein, T. ; Baer, R. ; Kümmel, S. Communication: Tailoring the optical gap in light-harvesting molecules. J. Chem. Phys. 2011, 134, 151101.Abstract

Systematically varying the optical gap that is associated with charge-transfer excitations is an important step in the design of light-harvesting molecules. So far the guidance that time-dependent density functional theory could give in this process was limited by the traditional functionals' inability to describe charge-transfer excitations. We show that a nonempirical range-separated hybrid approach allows to reliably predict charge-transfer excitations for molecules of practically relevant complexity. Calculated absorption energies agree with measured ones. We predict from theory that by varying the number of thiophenes in donor-acceptor-donor molecules, the energy of the lowest optical absorption can be tuned to the lower end of the visible spectrum. Saturation sets in at about five thiophene rings. (C) 2011 American Institute of Physics. [doi:10.1063/1.3581788]

karolewski2011.pdf
2010
Paul, A. K. ; Adhikari, S. ; Baer, M. ; Baer, R. H2 + photodissociation by an intense pulsed photonic Fock state. Phys. Rev. A 2010, 81, 013412.Abstract

We study the photodissociation of the H+2 molecule by ultrashort Fock-state electromagnetic pulses (EMPs). We use the Born-Oppenheimer treatment combined with an explicit photon number representation via diabatic electrophoton potential surfaces for simplification of the basic equations. We discuss the issue of the number of photon states required and show that six photon states enable good accuracy for photoproduct kinetic energies of up to 3 eV. We calculate photodissociation probabilities and nuclear kinetic-energy (KE) distributions of the photodissociation products for 800 nm, 50-TW/cm2 pulses. We show that KE distributions depend on three pulse durations of 10, 20, and 45 fs and on various initial vibrational states of the molecule. We compare the Fock-state results to those obtained by “conventional,” i.e., coherent-state, laser pulses of equivalent electric fields and durations. The effects of the quantum state of EMPs on the photodissociation dynamics are especially strong for high initial vibrational states of H+2. While coherent-state pulses suppress photodissociation for the high initial vibrational states of H+2, the Fock-state pulses enhance it.

paul2010.pdf
Rabani, E. ; Baer, R. Theory of multiexciton generation in semiconductor nanocrystals. Chem. Phys. Lett. 2010, 496, 227–235.Abstract

We develop a generalized framework based on a Green’s function formalism to calculate the efficiency of multiexciton generation in nanocrystal quantum dots. The direct/indirect absorption and coherent/incoherent impact ionization mechanisms, often used to describe multiexciton generation in nanocrystals, are reviewed and rederived from the unified theory as certain approximations. In addition, two new limits are described systematically – the weak Coulomb coupling limit and the semi-wide band limit. We show that the description of multiexciton generation in nanocrystals can be described as incoherent process and we discuss the scaling of multiexciton generation with respect to the photon energy and nanocrystal size. Illustrations are given for three prototype systems: CdSe, InAs and silicon quantum dots.

rabani2010.pdf
Baer, R. ; Livshits, E. ; Salzner, U. Tuned Range-separated hybrids in density functional theory. Annu. Rev. Phys. Chem. 2010, 61, 85–109. Publisher's VersionAbstract

We review density functional theory (DFT) within the Kohn-Sham (KS) and the generalized KS (GKS) frameworks from a theoretical perspective for both time-independent and time-dependent problems. We focus on the use of range-separated hybrids within a GKS approach as a practical remedy for dealing with the deleterious long-range self-repulsion plaguing many approximate implementations of DFT. This technique enables DFT to be widely relevant in new realms such as charge transfer, radical cation dimers, and Rydberg excitations. Emphasis is put on a new concept of system-specific range-parameter tuning, which introduces predictive power in applications considered until recently too difficult for DFT.

baer2010a.pdf
2009
Stein, T. ; Kronik, L. ; Baer, R. Prediction of charge-transfer excitations in coumarin-based dyes using a range-separated functional tuned from first principles. J. Chem. Phys. 2009, 131, 244119–5.Abstract

We study the description of charge-transfer excitations in a series of coumarin-based donor-bridge-acceptor dyes. We show that excellent predictive power for the excitation energies and oscillator strengths in these systems is obtained by using a range-separated hybrid functional within the generalized Kohn–Sham approach to time-dependent density functional theory. Key to this success is a step for tuning the range separation parameter from first principles. We explore different methods for this tuning step, which are variants of a recently suggested approach for charge-transfer excitations [T. Stein et al., J. Am. Chem. Soc. 131, 2818 (2009)]. We assess the quality of prediction by comparing to excitation energies previously published for the same systems using the approximate coupled-cluster singles and doubles (CC2) method.

stein2009.pdf
Stein, T. ; Kronik, L. ; Baer, R. Reliable Prediction of Charge Transfer Excitations in Molecular Complexes Using Time-Dependent Density Functional Theory. J. Am. Chem. Soc. 2009, 131, 2818–2820.Abstract

We show how charge transfer excitations at molecular complexes can be calculated quantitatively using time-dependent density functional theory. Predictive power is obtained from range-separated hybrid functionals using nonempirical tuning of the range-splitting parameter. Excellent performance of this approach is obtained for a series of complexes composed of various aromatic donors and the tetracyanoethytene acceptor, paving the way to systematic nonempirical quantitative studies of charge-transfer excitations in real systems.

stein2009a.pdf
Paul, A. K. ; Adhikari, S. ; Mukhopadhyay, D. ; Halasz, G. J. ; Vibok, A. ; Baer, R. ; Baer, M. Photodissociation of H2+ upon Exposure to an Intense Pulsed Photonic Fock State. J. Phys. Chem. A 2009, 113, 7331–7337.Abstract

Producing and controlling nonclassical light states are now the subject of intense experimental efforts. In this paper we consider the interaction of such a light state with a small molecule. Specifically, we develop the theory and apply it numerically to calculate in detail how a short pulse of nonclassical light, such as the high intensity Fock state, induces photodissociation in H2+. We compare the kinetic energy distributions and photodissociation yields with the analogous results of quasi-classical light, namely a coherent state. We find that Fock-state light decreases the overall probability of dissociation for low vibrational states of H2+ as well as the location of peaks and line shapes in the kinetic energy distribution of the nuclei.

paul2009.pdf
Baer, R. Prevalence of the adiabatic exchange-correlation potential approximation in time-dependent density functional theory. Theochem-Journal of Molecular Structure 2009, 914, 19–21.Abstract

Time-dependent (TD) density functional theory (TDDFT) promises a numerically tractable account of many-body electron dynamics provided good simple approximations are developed for the exchange-correlation (XC) potential functional (XCPF). The theory is usually applied within the adiabatic XCPF approximation, appropriate for slowly varying TD driving fields. As the frequency and strength of these fields grows, it is widely held that memory effects kick in and the eligibility of the adiabatic XCPF approximation deteriorates irreversibly. We point out, however, that when a finite system of electrons in its ground-state is gradually exposed to a very a high-frequency and eventually ultra-strong homogeneous electric field, the adiabatic XCPF approximation is in fact rigorously applicable. This result shows that adiabatic XCPF has a larger scope of applicability than previously suspected and in this sense is compliant with recent numerical findings by Thiele et al. [M. Thiele, E.K.U. Gross, S. Kümmel, Phys. Rev. Lett. 100 (2008) 153004] of negligible memory effects in strong-field double ionization.

baer2009.pdf
Andzelm, J. ; Rinderspacher, B. C. ; Rawlett, A. ; Dougherty, J. ; Baer, R. ; Govind, N. Performance of DFT Methods in the Calculation of Optical Spectra of TCF-Chromophores. J. Chem. Theory Comput. 2009, 5 2835–2846.Abstract

We present electronic structure calculations of the ultraviolet/visible (UV?vis) spectra of highly active push?pull chromophores containing the tricyanofuran (TCF) acceptor group. In particular, we have applied the recently developed long-range corrected Baer-Neuhauser-Livshits (BNL) exchange-correlation functional. The performance of this functional compares favorably with other density functional theory (DFT) approaches, including the CAM-B3LYP functional. The accuracy of UV-vis results for these molecules is best at low values of attenuation parameters (\gamma) for both BNL and CAM-B3LYP functionals. The optimal value of \gamma is different for the charge-transfer (CT) and valence excitations. The BNL and PBE0 exchange correlation functionals capture the CT states particularly well, while the ???* excitations are less accurate and system dependent. Chromophore conformations, which considerably affect the molecular hyperpolarizability, do not significantly influence the UV?vis spectra on average. As expected, the color of chromophores is a sensitive function of modifications to its conjugated framework and is not significantly affected by increasing aliphatic chain length linking a chromophore to a polymer. For selected push?pull aryl-chromophores, we find a significant dependence of absorption spectra on the strength of diphenylaminophenyl donors.

andzelm2009.pdf
2008
Rabani, E. ; Baer, R. Distribution of multiexciton generation rates in CdSe and InAs nanocrystals. Nano Lett. 2008, 8 4488–4492.Abstract

The distribution of rates of multiexciton generation following photon absorption is calculated for semiconductor nanocrystals (NCs). The rates of biexciton generation are calculated using Fermi’s golden rule with all relevant Coulomb matrix elements, taking into account proper selection rules within a screened semiempirical pseudopotential approach. In CdSe and InAs NCs, we find a broad distribution of biexciton generation rates depending strongly on the exciton energy and size of the NC. Multiexciton generation becomes inefficient for NCs exceeding 3 nm in diameter in the photon energy range of 2-3 times the band gap.

rabani2008distribution.pdf
2007
Lopata, K. ; Neuhauser, D. ; Baer, R. Curve crossing and negative refraction in simulations of near-field coupled metallic nanoparticle arrays. J. Chem. Phys. 2007, 127, 154714–8.Abstract

We extend our previous results [R. Baer et al., J. Chem. Phys. 126, 014705 (2007).] to develop a simple theory of localized surface plasmon-polariton (LSPP) dispersion on regular arrays of metal nanoparticles in the weak-field and weak-damping limits. This theory describes the energy-momentum as well as the polarization-momentum properties of LSPP waves, both of which are crucial to plasmonic device design. We then explicitly compute the dispersion relation for isotropic and anisotropic two-dimensional square lattices, and show curve crossings between all three levels as well as negative refraction where the phase and group velocities (refractive indices), or at least their projection along the main axis, have different signs. The curve crossing implies that scattering between the different polarizations, and therefore different velocities, is easy at the curve crossing momenta, so that a quick change in wave packet direction can be achieved. Time-resolved wave packet dynamics simulations demonstrate negative refraction and the easy scattering over nanometer length scales. This paper also gives some computational schemes for future applications, such as a way to include source terms and how to efficiently treat dissipative effects.

lopata2007.pdf
Baer, R. ; Lopata, K. ; Neuhauser, D. Properties of phase-coherent energy shuttling on the nanoscale. J. Chem. Phys. 2007, 126, 014705–13.Abstract

Recently, the possibility of transporting electromagnetic energy as local-plasmon-polariton waves along arrays of silver nanoparticles was demonstrated experimentally [S. A. Maier et al., Nat. Mater. 2, 229 (2003)]. It was shown that dipole coupling facilitates phase-coherent excitation waves, which propagate while competing against decoherence effects occurring within each dot. In this article the authors study the ideal coherent shuttling in such a system, leaving decoherence for future investigation. In the weak field limit, the waves obey a Schrödinger equation, to be solved using either time-dependent wave-packet or energy resolved scattering techniques. The authors study some dynamical characteristics of these waves, emphasizing intuition and insight. Scattering from barriers, longitudinal-transverse coupling and acceleration methods are studied in detail. The authors also discuss briefly two-dimensional arrays and a simple decoherence model

baer2007.pdf
2006
Livshits, E. ; Baer, R. Time-dependent density-functional studies of the D2 Coulomb explosion. J. Phys. Chem. A 2006, 110, 8443–8450. Publisher's VersionAbstract

Real-time first principle simulations are presented of the D2 Coulomb explosion dynamics detonated by exposure to very intense few-cycle laser pulse. Three approximate functionals within the time-dependent density functional theory (TDDFT) functionals are examined for describing the electron dynamics, including time-dependent Hartree-Fock theory. Nuclei are treated classically with quantum corrections. The calculated results are sensitive to the underlying electronic structure theory, showing too narrow kinetic energy distribution peaked at too high kinetic energy when compared with recent experimental results (Phys. Rev. Lett. 2003, 91, 093002). Experiment also shows a low energy peak which is not seen in the present calculation. We conclude that while Ehrenfest-adiabatic-TDDFT can qualitatively account for the dynamics, it requires further development, probably beyond the adiabatic approximation, to be quantitative.

livshits2006.pdf
2005
Shemesh, D. ; Baer, R. ; Seideman, T. ; Gerber, B. R. Photoionization dynamics of glycine adsorbed on a silicon cluster:“On-the-fly” simulations. The Journal of chemical physics 2005, 122, 184704.Abstract

Dynamics of glycine chemisorbed on the surface of a silicon cluster is studied for a process that involves single-photon ionization, followed by recombination with the electron after a selected time delay. The process is studied by “on-the-fly” molecular dynamics simulations, using the semiempirical parametric method number 3 (PM3) potential energy surface. The system is taken to be in the ground state prior to photoionization, and time delays from 5 to 50 fs before the recombination are considered. The time evolution is computed over 10 ps. The main findings are (1) the positive charge after ionization is initially mostly distributed on the silicon cluster. (2) After ionization the major structural changes are on the silicon cluster. These include Si–Si bond breaking and formation and hydrogen transfer between different silicon atoms. (3) The transient ionization event gives rise to dynamical behavior that depends sensitively on the ion state lifetime. Subsequent to 45 fs evolution in the charged state, the glycine molecule starts to rotate on the silicon cluster. Implications of the results to various processes that are induced by transient transition to a charged state are discussed. These include inelastic tunneling in molecular devices, photochemistry on conducting surfaces, and electron-molecule scattering.

shemesh2005photoionization.pdf
2004
Baer, R. ; Seideman, T. ; Ilani, S. ; Neuhauser, D. Ab initio study of the alternating current impedance of a molecular junction. J. Chem. Phys. 2004, 120, 3387–3396.Abstract

The small-bias conductance of the C-6 molecule, stretched between two metallic leads, is studied using time-dependent density functional theory within the adiabatic local density approximation. The leads are modeled by jellium slabs, the electronic density and the current density are described on a grid, whereas the core electrons and the highly oscillating valence orbitals are approximated using standard norm-conserving pseudopotentials. The jellium leads are supplemented by a complex absorbing potential that serves to absorb charge reaching the edge of the electrodes and hence mimic irreversible flow into the macroscopic metal. The system is rapidly exposed to a ramp potential directed along the C-6 axis, which gives rise to the onset of charge and current oscillations. As time progresses, a fast redistribution of the molecular charge is observed, which translates into a direct current response. Accompanying the dc signal, alternating current fluctuations of charge and currents within the molecule and the metallic leads are observed. These form the complex impedance of the molecule and are especially strong at the plasmon frequency of the leads and the lowest excitation peak of C-6. We study the molecular conductance in two limits: the strong coupling limit, where the edge atoms of the chain are submerged in the jellium and the weak coupling case, where the carbon atoms and the leads do not overlap spatially. (C) 2004 American Institute of Physics.

baer2004c.pdf
2003
Neuhauser, D. ; Baer, R. A two-grid time-dependent formalism for the Maxwell equation. Journal of Theoretical & Computational Chemistry 2003, 2 537–546. neuhauser2003.pdf
2000
Barash, D. ; Orel, A. E. ; Baer, R. A comment on the stabilization of a one-dimensional short-range model atom in intense laser fields. Journal of Physics B-Atomic Molecular and Optical Physics 2000, 33, 1279–1282. barash2000a.pdf
Barash, D. ; Orel, A. E. ; Baer, R. Laser-induced resonance states as dynamic suppressors of ionization in high-frequency short pulses. Phys. Rev. A 2000, 61, 013402.Abstract

An adiabatic-Floquet formalism is used to study the suppression of ionization in short laser pulses. In the high-frequency limit the adiabatic equations involve only the pulse envelope where transitions are purely ramp effects. For a short-ranged potential having a single-bound state we show that ionization suppression is caused by the appearance of a laser-induced resonance state, which is coupled by the pulse ramp to the ground state and acts to trap ionizing flux.

barash.pdf

Pages